pKw[1] is the negative log of Kw, which is the equilibrium of water. Equilibrium of water is the multiplication of the hydronium ion (H+) and the hydroxide ion (OH-), equaling to 1.0x10-14. The negative log of Kw is 14, which is also the total of pH and pOH/
The equation is
[2]
where
[1]https://en.wikipedia.org/wiki/Self-ionization_of_water
[2]Whitten, et al. 10th Edition. Pp.713