From UCDavis Chemwiki
Early in the history of chemistry it was noted that aqueous solutions of a number of substances behaved very similarly, although the substances themselves did not at first seem to be related. Scientist began to search for related properties which could be used to classify solutions. For instance, solutions were classified as acids if they had the following characteristics: sour taste; ability to dissolve metals such as Zn, Mg, or Fe; ability to release a gas from solid limestone (CaCO3) or other carbonates; ability to change the color of certain dyes (litmus paper turns red in the presence of acid). Another group of substances called bases or alkalies can also be distinguished by the properties of their aqueous solutions.
These have a bitter taste, slippery or soapy feel, and the ability to change the color of certain dyes (litmus paper turns blue in base). Most important of all, acids and bases appear to behave as opposites. Any acid can counteract or neutralize the properties of a base (neutralization is the reaction of H+ with OH- to form H2O molecules). Similarly any base can neutralize an acid.