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Equilibrium Constant (K)

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Aug 5, 2022, 2:34:36 PM
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May 19, 2016, 5:14:38 PM
Kc=[P]y[R]x
[P]Concentration
[R]Concentration
(y)Coefficient 1
(x)Coefficient 2
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The Equilibrium Constant formula, K= [P]y / [R]x, is used to calculate the reaction quotient when a reaction has reached equilibrium. Calculating equilibrium constants can help determine the composition of a system while it is at equilibrium. A typical equation, xR = yP, can be used to represent the equilibrium constant formula because [products] are always in the numerator, with [reactants] in the denominator. Therefore, the product "P" belongs in the numerator with reactant "R" in the denominator. Each variable is raised to its respective equation coefficient, y and x. The input variables are coefficients x and y (unit-less) and the concentrations of [P] and [R] in mols/L.   

Setting K against Q can provide useful information about which direction a reaction will proceed. It gives five possibilities:

  • Q = K      The system is at equilibrium and does not shift left or right
  • Q = 0       The system will shift forward/to the right (towards products)
  • Q < K       There are more reactants than products, thus the system will shift to the right (towards products)
  • Q > K      There are more products than reactants, thus the system will shift to the left (towards reactants)
  • Q = infinity (Q >>> K) The system will shift left (towards reactants)

Example:

aA + bB = dD + eE

Kc = [products] / [reactants]

Kc = [E]e [D]d / [B]b [A]a

References

Source: Wikipedia 


This equation, Equilibrium Constant (K), is used in 3 pages
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